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Detecting ASR
ASTM C295

When performed by a skilled petrographer knowledgeable about concrete, this method can be very reliable in
identifying the mineralogical phases that are susceptible to ASR. The examination can’t predict if potentially reactive materials will produce harmful expansions. particularly for fine aggregates that have shown deleterious reactions in the field.

ASTM C1293

Considered by many to be the most trustworthy test for reactivity, this test unfortunately requires one year to
yield meaningful results. It may give false negatives, particularly for fine aggregates that have shown deleterious reactions in the field.

ASTM C227

This method can fail to show a material to be reactive, even though the material has proven to be reactive in field use.

ASTM C1260

ASR appears most often as “Y-shaped” cracks that join to create a map-cracking pattern (Fig. 3). The crack
pattern, however, is also related to stress distribution as affected by restraint. Cracks caused by ASR expansion tend to align parallel to the direction of maximum restraint. In a pavement, for instance, the prominent
This method will correctly identify most aggregates that have a potential for reaction, if low enough expansion
limits are used. This test method has indicated potential reactivity for some aggregates in the laboratory although the aggregates have no history of deleterious reaction in the field. This may simply indicate that the
aggregates were not used in a situation that would lead to deleterious reaction.

Test Methods for Identifying ASR Distress. It is important to distinguish between the reaction and damage resulting from the reaction. In the diagnosis of concrete deterioration, it is most likely that a gel product will be identified. But, in some cases significant amounts of gel are formed without causing damage to concrete. To pinpoint ASR as the cause of damage, the presence of deleterious ASR gel must be verified. A site of expansive reaction can be defined as an aggregate particle that is recognizably reactive or potentially reactive and is at least partially replaced by gel. Gel can be present in cracks and voids and may also be present in a ring surrounding an aggregate particle at its edges. A network of internal cracks connecting reacted aggregate particles is an almost certain indication that ASR is responsible for cracking. A petrographic examination (ASTM C 856) is the most positive method for identifying ASR gel in concrete (Powers 1999). Petrography, when used to study a known reacted concrete, can confirm the presence of reaction products and verify ASR as an underlying cause of deterioration
Q: How can I test for alkali-silica reactivity (ASR)?

A: Alkali-silica reactivity is the process in which certain minerals (mostly glass type silica) in the presence of moisture are broken down by the highly alkaline environment of concrete producing a gel that expands creating tensile forces in the concrete matrix which cause cracking of the concrete. The cracking then allows more water to infiltrate into the concrete creating more gel, more expansion etc. Ultimately the concrete fails or disintegrates.

Table: Test Methods for Alkali-Silica Reactivity (Source: Farny and Kosmatka, 1997)
Test Name Purpose Type of Test Duration of Test Comments
ASTM C 227,
Potential alkali-reactivity of cement-aggregate combinations (mortar-bar method)
To test the susceptibility of cement-aggregate combinations to expansive reactions involving alkalies Mortar bars stored over water at 37.8°C (100°F) and high relative humidity Varies: first measurement at 14 days, then 1, 2, 3, 4, 6, 9, and 12 months; every 6 months after that as necessary Test may not produce significant expansion, especially for carbonate aggregate. Long test duration. Expansions may not be from ASR.
ASTM C 289,
Potential alkali-silica reactivity of aggregates
To determine potential reactivity of siliceous aggregates Sample reacted with alkaline solution at 80°C (176°F). 24 hours Quick results. Some aggregates give low expansions even though they have high silica content. Not reliable.
ASTM C 294,
Constituents of natural mineral aggregates
To give descriptive nomenclature for the more common or important natural minerals—an aid in determining their performance Visual identification Short duration—as long as it takes to visually examine the sample These descriptions are used to characterize naturally-occurring minerals that makeup common aggregate sources.
ASTM C 295,
Petrographic examination of aggregates for concrete
To outline petrographic examination procedures for aggregates—an aid in determining their performance Visual and microscopic examination of prepared samples—sieve analysis, microscopy, scratch or acid tests Short duration—visual examination does not involve long test periods Usually includes optical microscopy. Also may include XRD analysis, differential thermal analysis, or infrared spectroscopy—see ASTM C 294 for descriptive nomenclature.
ASTM C 342,
Potential volume change of cement-aggregate combinations
To determine the potential ASR expansion of cement-aggregate combinations Mortar bars stored in water at 23°C (73.4°F) 52 weeks Primarily used for aggregates from Oklahoma, Kansas, Nebraska, and Iowa.
ASTM C 441,
Effectiveness of mineral admixtures or GBFS in preventing excessive expansion of concrete due to alkali-silica reaction
To determine effectiveness of supplementary cementing materials in controlling expansion from ASR Mortar bars—using Pyrex glass as aggregate—stored over water at 37.8°C (100°F) and high relative humidity Varies: first measurement at 14 days, then 1, 2, 3, 4, 5, 9, and 12 months; every 6 months after that as necessary Highly reactive artificial aggregate may not represent real aggregate conditions. Pyrex contains alkalies.
ASTM C 856,
Petrographic examination of hardened concrete
To outline petrographic examination procedures for hardened concrete—useful in determining condition or performance Visual (unmagnified) and microscopic examination of prepared samples Short duration — includes preparation of samples and visual and microscope examination Specimens can be examined with stereo microscopes, polarizing microscopes, metallographic  microscopes, and scanning electron microscope.
ASTM C 856 (AASHTO T 299),
Annex uranyl- acetate treatment procedure
To identify products of ASR in hardened concrete Staining of a freshly-exposed concrete surface and viewing under UV light Immediate results Identifies small amounts of ASR gel whether they cause expansion or not. Opal, a natural aggregate, and carbonated paste can glow—interpret results accordingly. Tests must be supplemented by petrographic examination and physical tests for determining concrete expansion
Los Alamos staining method (Powers 1999) To identify products of ASR in hardened concrete. Staining of a freshly-exposed concrete surface with two different reagents. Immediate results
ASTM C 1260 (AASHTOT303),
Potential alkali reactivity of aggregates (mortar-bar method)
To test the potential for deleterious alkali-silica reaction of aggregate in mortar bars Immersion of mortar bars in alkaline solution at 80°C (176°F) 16 days Very fast alternative to C 227. Useful for slowly reacting aggregates or those that produce expansion late in the reaction.
ASTM C 1293,
Determination of length change of concrete due to alkali-silica reaction (concrete prism test)
To determine the potential ASR expansion of cement-aggregate combinations. Concrete prisms stored over water at 38°C (100.4°F) Varies: first measurement at 7 days, then 28and 56 days, then 3,6,9,and 12 months; every 6 months as after that as necessary Requires long test duration for meaningful results. Use as a supplement to C 227,C 295, C 289, and C 1260. Similar to CSA A23.2-14A.
Accelerated concrete prism test (modified ASTM C 1293) To determine the potential ASR expansion of cement-aggregate combinations. Concrete prisms stored over water at 60°C(140°F) 3 month (91 days) Fast alternative to C 227. Good correlation to ASTM C 227 for carbonate and sedimentary rocks.
  ASR Test